Đáp án D

m_X = m_C + m_H + m_O  + m_Na =  12 ( n N a 2 C O 3 + n C O 2 ) + 2 n H 2 O + 23.2. n N a 2 C O 3 + m O

Þ 12.(0,15 + 0,05) + 2.0,15 + 46.0,05 + m_O = 8,2

Þ m_O = 3,2 gam

\(n_{CO_2}=\dfrac{17,6}{44}=0,4\left(mol\right)\)

Bảo toàn C: n_C = 0,4 (mol) => m_C = 0,4.12 = 4,8(g)

\(n_{H_2O}=\dfrac{8,1}{18}=0,45\left(mol\right)\) 

Bảo toàn H: n_H = 0,9 (mol) => m_H = 0,9.1 = 0,9 (g)

\(n_{N_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

Bảo toàn N: n_N = 0,1 (mol) => m_N = 0,1.14 = 1,4 (g)

\(n_C=\dfrac{24,64}{22,4}+\dfrac{10,6}{106}=1,2\left(mol\right)\)

\(\Rightarrow m_C=14,4\left(g\right)\)

\(n_{CO_2}=\dfrac{5.28}{44}=0.12\left(mol\right)\Rightarrow n_C=0.12\left(mol\right)\Rightarrow m_C=0.12\cdot12=1.44\left(g\right)\)

\(n_{H_2O}=\dfrac{0.9}{18}=0.05\left(mol\right)\Rightarrow n_H=0.05\cdot2=0.1\left(mol\right)\)

\(n_{N_2}=\dfrac{0.224}{22.4}=0.01\left(mol\right)\Rightarrow n_N=0.02\left(mol\right)\Rightarrow m_N=0.02\cdot14=0.28\left(g\right)\)

\(m_O=m_A-m_C-m_H-m_N=2.46-1.44-0.1-0.28=0.64\left(g\right)\)

\(\%C=\dfrac{1.44}{5.28}\cdot100\%=27.27\%\)

\(\%H=\dfrac{0.1}{5.28}\cdot100\%=1.89\%\)

\(\%N=\dfrac{0.28}{5.28}\cdot100\%=5.3\%\)

\(\%O=65.54\%\)

Em làm tương tự như câu lúc nãy nhé !

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ ĐLBTKL:m_{tg}=m_{sp}=m_X+m_{O_2}=m_{CO_2}+m_{H_2O}=9+0,3.32=18,6\left(g\right)\\ n_{CO_2}:n_{H_2O}=1:1\Rightarrow n_{CO_2}=n_{H_2O}\\ Đặt:n_{CO_2}=n_{H_2O}=t\left(mol\right)\left(t>0\right)\\ \Rightarrow44t+18t=18,6\\ \Leftrightarrow t=0,3\left(mol\right)\\ \Rightarrow n_C=n_{CO_2}=0,3\left(mol\right);n_H=2.0,3=0,6\left(mol\right)\\ Trong.X:m_C=0,3.12=3,6\left(g\right);m_H=0,6.1=0,6\left(g\right)\\ Vì:m_C+m_H=3,6+0,6=4,2< 9\\ \Rightarrow X.chắc.chắn.có.O\\ \Rightarrow X.có:C,H,O\\ m_O=9-4,2=4,8\left(g\right)\\ n_O=\dfrac{4,8}{16}=0,3\left(mol\right)\)

\(b,Đặt.CTĐGN:C_iH_dO_q\left(i,d,q:nguyên,dương\right)\\ Ta.có:i:d:q=0,3:0,6:0,3=1:2:1\\ \Rightarrow CTĐGN:CH_2O\\ c,Ta.có:9< d_{\dfrac{X}{He}}< 21\\ \Leftrightarrow9< \dfrac{M_X}{4}< 21\\ \Leftrightarrow36< M_X< 84\\ Đặt.CTTQ:\left(CH_2O\right)_a\left(a:nguyên,dương\right)\\ \Leftrightarrow36< 30a< 84\\ \Leftrightarrow1,2< a< 2,8\\ \Rightarrow a=2\\ \Rightarrow CTPT:C_2H_4O_2\)

Chúc em học tốt!

n O2 = 4,2/22,4 = 0,1875(mol)

n C = n CO2 = 6,6/44 = 0,15(mol)

n H2O = 2,25/18 = 0,125(mol)

=> n H = 2n H2O = 0,25(mol)

Ta có :

%C = m C / m X  .100% = 0,15.12/2,85  .100% = 63,15%

%H = m H / m X  .100% = 0,25.1/2,85  .100% = 8,77%

%O = 100% -63,15% -8,77% = 28,08%

Đáp án D

Đáp án A